期刊
TOPICS IN CATALYSIS
卷 52, 期 3, 页码 304-314出版社
SPRINGER/PLENUM PUBLISHERS
DOI: 10.1007/s11244-008-9153-5
关键词
Catalysis; 5-Hydroxymethyl-2-furfural; Diformylfurane; PVP; Vanadyl
资金
- Spanish Ministry of Education and Science [MAT 2006-14274-C02-01]
- Spanish Council for Scientific Research (CSIC)
Diformylfurane (DFF) has been obtained by aerobic oxidation of 5-hydroxymethyl-2-furaldehyde (HMF) with homogeneous pyridine-vanadyl complexes in homogeneous phase, with Cu and V in poly(4-vinylpyridine) crosslinked with 33% divinylbenzene (PVP) and supported on organofunctionalized SBA-15 mesoporous materials. Detailed spectroscopic characterization of the materials is provided. Catalytic results show that pyridine-vanadyl complexes supported on SBA-15 are less active than when in the polymeric form. The nature of the catalyst surface and solvent plays a key role on the catalytic behaviour.
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