期刊
THIN SOLID FILMS
卷 518, 期 1, 页码 138-146出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.tsf.2009.06.010
关键词
Photoelectrochemical reduction; Nitrate; Rhenium; Electrodeposition, silicon; Intensity modulated photocurrent spectroscopy; Electrical properties and measurements
类别
资金
- FONDECYT, Chile [11060514, 7080186]
- Direccion de investigacion e Innovacion of the Pontificia Universidad Catolica de Valparaiso [037.108/2008 DII-PUCV]
In this study we examined the rhenium electrodeposition process onto p-Si(100) from acidic media. The study was carried out by means of cyclic voltammetry and the potential-steps method from which the corresponding nucleation and growth mechanism were determined. Both methods were performed under illumination using a solar simulator for electron photogeneration. A 3D progressive nucleation, diffusion-controlled growth of rhenium films was found. Likewise, a morphologic analysis was completed for the deposits obtained at different potential values by means of atomic force microscopy. An energetic characterization through capacitance measurements (Mott-Schottky plots and parallel capacitance) of the pSi/NO(3)(-) and p-Si/Re/NO(3)(-) interfaces was done. The photoelectrochemical reduction of nitrate ions, PERN, on the different p-Si/Re electrode systems synthesized was studied. An overpotential decrease of 0.3 V and a photocurrent increase for the PERN on p-Si (100)/Re electrode systems compared with p-Si(100) and metallic Re was found. Finally, the kinetic parameters of the cathodic reactions in the p-Si and p-Si/Re acidic media were estimated using intensity modulated photocurrent spectroscopy. A brief analysis from this technique was done. According to these results, the p-Si/Re electrode system could be a potential photoelectrocatalyst for the PERN. (C) 2009 Elsevier B.V. All rights reserved.
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