期刊
SCIENTIFIC WORLD JOURNAL
卷 -, 期 -, 页码 -出版社
HINDAWI PUBLISHING CORPORATION
DOI: 10.1100/2012/632910
关键词
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资金
- Key Field Project of the Knowledge Innovation Program, Chinese Academy of Sciences [Y234081A07]
- Team Program Project and a general project of the National Natural Science Foundation of China [41121063, 40972222]
- Earmarked Foundation of the State Key Laboratory [SKLOG2009A04]
- State Science and Technology Ministry of China
To examine spatial distribution and bioconcentration of PAHs, water and fish samples were collected from Pearl River Delta in summer and spring, respectively. Particulate organic carbon, dissolved organic carbon, biodegradable DOC (BDOC), and chlorophyll a were measured. PAHs were dominated by 2- and 3-ring compounds in the water and SPM samples. Aqueous and solid-phase PAHs, respectively, showed significant correlations with total organic matter (TOC) in SPM or dissolved organic matter (DOC) in the water. The in-situ partitioning coefficients (log K-oc, mL/g) for the samples were observed to be related to log K-ow, implying that the hydrophobicity of PAHs is a critical factor in their distribution. It was also observed that BCF increased with the increasing K-ow in the viscera of tilapia (log BCF = 0.507 log K-ow - 1.368, r = 0.883). However, most of the observed log BCF values in other different fish tissues at first increased with the increasing of log K-ow, then reached a maximum value when log K-ow is between 5 and 7, and then decreased when log K-ow is higher than 7, indicating that the value of BCF may vary due to the diversity of fish species.
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