期刊
THERMOCHIMICA ACTA
卷 479, 期 1-2, 页码 1-6出版社
ELSEVIER
DOI: 10.1016/j.tca.2008.08.016
关键词
Hydrotalcite; Pyroaurite; Carbonate; X-ray diffraction; Thermal analysis
资金
- Queensland Research and Development Centre (QRDC-Alcan)
- Queensland University of Technology Inorganic Materials Research Program of the School of Physical and Chemical Sciences
- Australian Research Council (ARC)
Thermal analysis complimented with evolved gas mass spectrometry has been applied to hydrotalcites of the pyroaurite-stitchtite series containing the carbonate anion prepared by co-precipitation and with varying Fe3+, Cr3+ trivalent cation ratio. The resulting materials were characterised by XRD, and TGA/DTG to determine the stability of the hydrotalcites synthesised. Hydrotalcites of formula Mg-6(Cr-0.8,Fe-0.2)(2) (OH)(16) (CO3)center dot xH(2)O, Mg-6(Cr-0.6,Fe-0.4)(2) (OH)(16) (CO3)center dot xH(2)O, Mg-6(Cr0.4Fe0.6)(2) (OH)(16) (CO3)center dot xH(2)O and Mg-6(Cr-0.2,Fe-0.8)(2) (OH)(16) (CO3)center dot xH(2)O formed by intercalation with the carbonate anion as a function of Fe3+, Cr3+ trivalent cationic ratio show variation in the d-spacing attributed to the size of the cation. The thermal decomposition of stitchtite-pyroaurite solid Solution follows the following steps: (a) removal of adsorbed water (<100 degrees C), (b) elimination of the interlayer structural water (100-150 degrees C), and (c) the simultaneous dehydroxylation and decarbonation of the hydrotalcite framework (300-400 degrees C). The effect of replacement of Cr3+ by Fe3+ has no effect on the dehydroxylation temperature. The ion Current Curves provide evidence for the formation of Fe3+ and C3+ carbonates during dehydroxylation. Dehydroxylation results in the collapse of the hydrotalcite structure to that of its corresponding metal oxides, and results in the formation of spinels, including MgO, MgFe2O4, MgCr2O4 and MgFeAlO4. (c) 2008 Elsevier B.V. All rights reserved.
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