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To what question is the clamped-nuclei electronic potential the answer?

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THEORETICAL CHEMISTRY ACCOUNTS
卷 127, 期 3, 页码 121-131

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SPRINGER
DOI: 10.1007/s00214-009-0594-0

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An examination is made of how the nuclear motion Hamiltonian arises from a consideration of solutions to the eigenvalue problem for the full Coulomb Hamiltonian and the role played by the usual clamped-nuclei electronic Hamiltonian in the construction of such solutions.

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