期刊
TETRAHEDRON-ASYMMETRY
卷 25, 期 8, 页码 596-601出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2014.03.015
关键词
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资金
- Natural Science Foundation of China [21376213]
- Research Fund for the Doctoral Program of Higher Education of China [20120101110062]
- Low Carbon Fatty Amine Engineering Research Center of Zheijiang Province [2012E10033]
A new type of carbohydrate-derived pyridinecarboxylic organocatalyst was prepared by fine-tuning a D-glucosamine backbone at the C-2 and C-3 positions. The carbohydrate-derived pyridinecarboxylic organocatalyst was used for the enantioselective reduction of imines with trichlorosilane. The reduction proceeded in high yield (up to 93%) and with moderate enantioselectivity (up to 75%). (C) 2014 Elsevier Ltd. All rights reserved.
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