期刊
TETRAHEDRON-ASYMMETRY
卷 24, 期 19, 页码 1189-1192出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2013.08.005
关键词
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资金
- CREST project of the Japan Science and Technology Corporation (JST)
- Ministry of Education, Culture, Sports, Science and Technology (MEXT), Japan
- JST, Advanced Catalytic Transformation Program for Carbon Utilization (ACT-C)
- Grants-in-Aid for Scientific Research [24105518, 24590009, 13J07348, 24106726] Funding Source: KAKEN
The introduction of a 1,3-propanediamine unit at the 3-position of (S)-BINOL using a methylene spacer led to the formation of a chiral bifunctional organocatalyst for the aza-Morita-Baylis-Hillman (aza-MBH) reaction. The organocatalyst 1k mediated aza-MBH transformations with high chemical yields and with up to 82% ee. (C) 2013 Elsevier Ltd. All rights reserved.
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