期刊
TETRAHEDRON-ASYMMETRY
卷 24, 期 15-16, 页码 919-924出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2013.07.004
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资金
- Department of Science & Technology, Government of India, New Delhi [SR/S1/OC-60/2006]
- University Grants Commission, New Delhi
Enantioselective fluorination of aliphatic cyclic and acyclic beta-ketoesters was achieved in excellent yield (up to 98%) with moderate to good enantioselectivities (up to 86% ee) using tartrate derived bidentate bioxazoline-Cu(II) complexes. This is the first report of a bioxazoline which forms a 5-membered chelate inducing enantioselectivity in the asymmetric fluorination of beta-ketoesters. (C) 2013 Elsevier Ltd. All rights reserved.
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