期刊
TETRAHEDRON-ASYMMETRY
卷 22, 期 5, 页码 550-557出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.03.003
关键词
-
资金
- Ministry of Science and Technology of China [2009BAK61B04]
- Chinese Universities Scientific Fund [2010JS030]
A series of novel heteroarylidene malonate derived bis(thiazoline) ligands 1 and 2 were synthesized and applied to a Friedel-Crafts reaction between indole and alkylidene malonate. The Cu(OTf)(2) complex of ligand 2b bearing a benzyl group afforded moderate to excellent enantioselectivity for the adducts (up to >99% ee). (C) 2011 Elsevier Ltd. All rights reserved.
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