期刊
TETRAHEDRON-ASYMMETRY
卷 22, 期 12, 页码 1312-1319出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.07.018
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资金
- Board of Research in Nuclear sciences (BRNS), Government of India [2009/37/25 BRNS]
- Council of Scientific and Industrial Research (CSIR), New Delhi
Two synthetic routes based on a Dotz benzannulation toward the enantioselective synthesis of naphthoquinone antibiotics (-)- and (+)-juglomycin A are described. The stereoinducing step is based on asymmetric dihydroxylation. The syntheses are completed in seven to eight steps from Fischer carbene 12. (C) 2011 Elsevier Ltd. All rights reserved.
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