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A Dotz benzannulation route to the enantioselective synthesis of (-)- and (+)-juglomycin A

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TETRAHEDRON-ASYMMETRY
卷 22, 期 12, 页码 1312-1319

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PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.07.018

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  1. Board of Research in Nuclear sciences (BRNS), Government of India [2009/37/25 BRNS]
  2. Council of Scientific and Industrial Research (CSIR), New Delhi

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Two synthetic routes based on a Dotz benzannulation toward the enantioselective synthesis of naphthoquinone antibiotics (-)- and (+)-juglomycin A are described. The stereoinducing step is based on asymmetric dihydroxylation. The syntheses are completed in seven to eight steps from Fischer carbene 12. (C) 2011 Elsevier Ltd. All rights reserved.

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