期刊
TETRAHEDRON-ASYMMETRY
卷 22, 期 4, 页码 480-486出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2011.02.002
关键词
-
资金
- Hungarian Scientific Research Fund (OTKA) [K 60284, K 67585, NF 72194]
Several novel 1.1'-bi-2-naphthyl-appended azacrown ethers with donor side-arms were synthesized and applied for the first time as chiral catalysts in the asymmetric Michael addition of an N-protected aminomethylenephosphonate onto acrylonitriles, resulting in high diastereoselectivity and enantioselectivity. The absolute configuration of the adduct was determined from its experimental and calculated CD spectra. (C) 2011 Elsevier Ltd. All rights reserved.
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