期刊
TETRAHEDRON-ASYMMETRY
卷 21, 期 9-10, 页码 1189-1190出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetasy.2010.04.006
关键词
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资金
- Sumitomo Foundation
- Nagoya University
- Tatematsu Foundation
The catalytic performance of C-1-symmetric chiral ammonium betaines in the enantioselective direct Mannich-type reaction of alpha-nitrocarboxylates with N-Boc imines has been investigated. The most effective catalyst structure has been identified; this provides a reliable synthetic route to a variety of enantiomerically enriched alpha-tetrasubstituted alpha,beta-diamino acid derivatives. (C) 2010 Elsevier Ltd. All rights reserved.
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