期刊
TETRAHEDRON LETTERS
卷 59, 期 42, 页码 3810-3815出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.09.019
关键词
Carboxylation; 5-Carboxyvanillate decarboxylase; Lignin-derived phenols; Decarboxylase; Whole-cell biocatalyst
资金
- National Natural Science Foundation of China [21690084, 21721004]
- CAS/SAFEA International Partnership Program for Creative Research Teams
Selective carboxylation of substituted phenols is realized in the presence of bicarbonate under ambient pressure by engineered Escherichia coil whole-cells expressing various hydroxybenzoate decarboxylases, leading to their corresponding ortho-hydroxybenzoates. This process may be further developed as an efficient route to upgrade lignin-derived phenolic compounds as valuable building blocks. (C) 2018 Elsevier Ltd. All rights reserved.
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