期刊
TETRAHEDRON LETTERS
卷 59, 期 43, 页码 3880-3883出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2018.09.031
关键词
Photochemistry; Aerobic oxidation; Phosphine; Phosphine oxidation; Visible light
资金
- Fundamental Research Funds for the Central Universities, Pioneering Project of Academy for Engineering and Technology, Fudan University [gyy2017-002]
We report herein a visible light-induced oxidation of triarylphosphines under aerobic condition with excellent functional group tolerance. In this transformation, the photo catalyst 4-phenylthioxanthone acted as a photosensitizer for the in situ generation of singlet oxygen. This new approach provided a cheaper and greener method for the preparation of phosphine oxide, showing great advantages in environmental protocols. (C) 2018 Elsevier Ltd. All rights reserved.
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