期刊
TETRAHEDRON LETTERS
卷 55, 期 19, 页码 3104-3107出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.04.001
关键词
Alkynes; C-H functionalization; Indoles; Olefination; Rhodium
资金
- Basic Science Research Program through the National Research Foundation of Korea (NRF) - Ministry of Education, Science and Technology [2013R1A2A2A01005249, 2013058800]
A rhodium-catalyzed oxidative C2-alkenylation of indoles containing a N-(p-tolyl)carboxamide group with substituted alkynes via C-C bond formation and subsequent C-N bond cleavage has been described. This protocol represents direct access to C2-alkenylated free (NH)-indoles, which are important building blocks in the synthesis of natural and pharmacological compounds. (C) 2014 Elsevier Ltd. All rights reserved.
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