期刊
TETRAHEDRON LETTERS
卷 55, 期 27, 页码 3697-3700出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.05.006
关键词
Organocatalysis; Conjugate addition; Primary amine; Thiourea; Nitroalkene
资金
- Startup Fund from South University of Science and Technology of China (SUSTC)
- National Natural Science Foundation of China (NSFC) [21302089]
A kind of simple primary amine thiourea organocatalysts was developed. And their application in asymmetric conjugate addition of ketone to nitroalkene was investigated. In the presence of the new primary amine-thiourea, the conjugate addition of ketone to nitroalkene proceeded smoothly to afford the 1,4-adducts in high yields with good enantioselectivities. (C) 2014 Elsevier Ltd. All rights reserved.
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