期刊
TETRAHEDRON LETTERS
卷 55, 期 50, 页码 6839-6843出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.10.082
关键词
Bromodifluoromethylation; Dibromodifluoromethane; Aromatic Grignard reagents; Difluorocarbene; Organofluorine compounds
The bromodifluoromethylation of aromatic Grignard reagents having electron-withdrawing groups with dibromodifluoromethane (CF2Br2) was developed. The reaction proceeded to give the corresponding (bromodifluoromethyl)benzene derivatives via a difluorocarbene-mediated mechanism. (C) 2014 Elsevier Ltd. All rights reserved.
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