期刊
TETRAHEDRON LETTERS
卷 55, 期 33, 页码 4576-4580出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2014.05.093
关键词
Fluorine; Allylic; Methodology; Alkene
资金
- NSF [CHE 1152996]
A one step, regioselective allylic fluorination of alkenes is reported in which electrophilic and nucleophilic sources of fluorine act synergistically to afford rearranged allylic fluorides over alternative vicinal dihalides. The reaction occurs under exceptionally mild conditions and without need for prefunctionalization or transition metal catalysts. The fluorination of cyclic alkenes and monoterpenes is highlighted, and preliminary mechanistic experiments reveal that dual (radical and ionic) pathways operate simultaneously. (C) 2014 Elsevier Ltd. All rights reserved.
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