期刊
TETRAHEDRON LETTERS
卷 55, 期 3, 页码 585-594出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.11.108
关键词
Trifluoromethylation; C(sp(3))-CF3 bonds; Transition-metal-catalyzed; Transition-metal-promoted
资金
- NSFC [21325208, 21172209, 21361140372]
- CAS [KJCX2-EW-J02]
- FRFCU [WK2060190025]
- SRFDP [20123402110051]
- CPSF [2011M500289, 2012T50078]
- Fok Ying Tung Education Foundation
In the past 5 years, transition-metal-mediated trifluoromethylation for the construction of various CF3-containing building blocks has been the focus of recent research in both industrial and academic communities. Progresses in the construction of C(sp(2))-CF3 bonds and C(sp)-CF3 have been well reviewed. This Letter will focus on the cases of transition-metal-mediated C(sp(3))-CF3 bond formation, which involves the trifluoromethylation of sp(3)-hybridized C-X bonds, alkyl organometallic reagents, sp(3)-hybridized C-H bonds, and alkene derivatives. (C) 2013 Published by Elsevier Ltd.
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