期刊
TETRAHEDRON LETTERS
卷 55, 期 7, 页码 1306-1309出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.12.101
关键词
Azomethine ylide; Cycloaddition; Alkylidene malonate; Chiral phosphine; Ferrocene ligand
资金
- Japan Society for the Promotion of Science (JSPS) [25410053]
- Grants-in-Aid for Scientific Research [25410053] Funding Source: KAKEN
AgOAc/ThioClickFerrophos complex-catalyzed 1,3-dipolar cycloaddition of glycine imino ester, the precursor of azomethine ylide, with aryl- and alkylidene malonates afforded the corresponding exo-cycloadducts, that is, proline ester derivatives in high yields with high enantiomeric excess (up to 99% ee). The reactions proceeded smoothly under base-free conditions demonstrating the bifunctional catalysis of the silver complex. (C) 2014 Elsevier Ltd. All rights reserved.
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