期刊
TETRAHEDRON LETTERS
卷 54, 期 33, 页码 4491-4496出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.06.040
关键词
Pyrimidine; Photoluminescence; Intramolecular charge transfer; Condensation; Dyes
Condensation of donor-substituted aldehydes on methylpyrimidine led to two series of fluorescent molecules depending on the position of the methyl group. Whereas highly emissive 4-arylvinylpyrimidine derivatives are well-known, this is the first example of fluorescent 2-arylvinylpyrimidine compounds. The optical properties of the two families have been thoroughly compared. Whereas the series derived from 2-methylpyrimidine exhibit a blue shift in absorption and emission in comparison with 4-arylvinylpyrimidine, the influence of the position is less predictable on the fluorescence quantum yield. These compounds also exhibit halochromism: when adding acid, a bathotromic shift is observed in absorption whereas an increase of the fluorescence intensity which is red-shifted except for amino derivatives (a progressive quench of emission is observed in these cases). An emission solvatochromism study has shown that a higher intramolecular charge transfer seems to occur in 2-arylvinylpyrimidines than in 4-arylvinylpyrimidines. (C) 2013 Elsevier Ltd. All rights reserved.
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