4.4 Article

Optical Pd2+ sensing by rhodamine hydrazone ligands: different stoichiometries in aqueous/nonaqueous environments

期刊

TETRAHEDRON LETTERS
卷 54, 期 33, 页码 4357-4361

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.05.094

关键词

Optical sensing; Palladium ion; Rhodamine hydrazone; Selectivity; Stoichiometry

资金

  1. NSF of China [21136002, 20923006, 21076032]
  2. National Basic Research Program of China [2009CB724706, 2013CB733702]
  3. National High Technology Research and Development Program of China (863 Program) [2011AA02A105]

向作者/读者索取更多资源

A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd2+). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd2+ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H2O and 1:1 in MeOH/DCM were observed for Pd2+/RPd1-c complexation. (c) 2013 Elsevier Ltd. All rights reserved.

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