期刊
TETRAHEDRON LETTERS
卷 54, 期 33, 页码 4357-4361出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.05.094
关键词
Optical sensing; Palladium ion; Rhodamine hydrazone; Selectivity; Stoichiometry
资金
- NSF of China [21136002, 20923006, 21076032]
- National Basic Research Program of China [2009CB724706, 2013CB733702]
- National High Technology Research and Development Program of China (863 Program) [2011AA02A105]
A series of rhodamine spiro-leuco compounds have been developed as fluorescence-enhanced sensors for optical sensing of palladium ion (Pd2+). The initial rhodamine hydrazone derivatives, RPd1-a, RPd1-b, and RPd1-c, display a good coordination to Pd2+ inducing the spirolactam-open reaction with a significant fluorescence enhancement and color generation. Different stoichiometry results, 1:2 in EtOH/H2O and 1:1 in MeOH/DCM were observed for Pd2+/RPd1-c complexation. (c) 2013 Elsevier Ltd. All rights reserved.
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