期刊
TETRAHEDRON LETTERS
卷 54, 期 52, 页码 7171-7174出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.10.107
关键词
Caged; Caged glutamate; Photolysis; Bond cleavage; TPA
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan [24109008, 21108516, 19350021]
- Tokuyama Science Foundation
- Grants-in-Aid for Scientific Research [21108516] Funding Source: KAKEN
'Caging' and 'uncaging' bioactive substrates are key techniques in studying a wide variety of biological processes. In the present study, two-types of novel caged glutamates with a two-photon absorption (TPA) core, that is, pi-extended coumarin, were synthesized and their photochemical release of glutamate was analyzed. The high yields of glutamate (>92%) were observed in the photolysis of compounds 1 and 10, respectively. (C) 2013 Elsevier Ltd. All rights reserved.
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