期刊
TETRAHEDRON LETTERS
卷 54, 期 38, 页码 5151-5154出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.06.022
关键词
Phenol; Aniline; Smiles rearrangement; One-pot synthesis
资金
- Ministry of Environment (KME) [412-111-008]
- National Research Foundation [NRF-2010-0029634]
- Ministry of Knowledge Economy (MKE), South Korea [R0000495]
A convenient one-pot synthesis of phenols to anilines using 2-chloroacetamide/K2CO3/DMF system catalyzed by KI via Smiles rearrangement has been described. The synthesis of extensive amino aromatic products from phenols containing electron withdrawing group, has been performed in moderate to excellent yields to demonstrate the potentiality of this method in bio-medicinal and pharmaceutical applications. (C) 2013 Elsevier Ltd. All rights reserved.
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