期刊
TETRAHEDRON LETTERS
卷 54, 期 44, 页码 5865-5868出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.08.077
关键词
Gold catalysis; Spiroacetals; Asymmetric synthesis; Chiral catalysts
The development of an asymmetric gold-catalysed dihydroalkoxylation strategy for the synthesis of the 3'H-spiro[chroman-2,1'-isobenzofuran] spiroacetal ring system 5 is described. Spiroacetal was generated in up to 87:13 enantiomeric ratio using chiral gold-phosphine complexes and chiral silver phosphate Ag(S)-TRIP. Crown Copyright (C) 2013 Published by Elsevier Ltd. All rights reserved.
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