期刊
TETRAHEDRON LETTERS
卷 54, 期 21, 页码 2633-2636出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.03.030
关键词
Heteroacene; Synthesis; Selective; Multi-response; Anion sensor; Combined process
资金
- AcRF Tier 1 from MOE [RG 18/09]
- AcRF Tier 2 from MOE [MOE2012-t2-1-019, ARC 20/12]
- CREATE program (Nanomaterials for Energy and Water Management) from NRF
- New Initiative Fund from NTU, Singapore
A novel heteroacene, 2-(2,3,4,5-tetrafluorophenyl)-1H-imidazo[4,5-b]phenazine has been successfully synthesized. The heteroacene can selectively detect F- over Cl-, Br-, I-, NO3-, HSO4-, ClO4-, and BF4- in organic solvents through colorimetric and fluorescent responses. The interaction between the heteroacene and F- was investigated through UV-Vis, fluorescence, and H-1 NMR titration experiments, which suggested that the effects might occur via a combined process including hydrogen bond, deprotonation, and anion-pi interactions between the sensor and F-. (c) 2013 Elsevier Ltd. All rights reserved.
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