期刊
TETRAHEDRON LETTERS
卷 54, 期 13, 页码 1718-1721出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.01.071
关键词
Organoselenium compounds; PEG-400; beta-Phenylselanylcarbonyl compounds; Michael adduct; alpha,beta-Carbonyl compounds
资金
- FAPERGS
- CNPq [PRONEX 10/0005-1, PRONEM 11/2026-4, PqG 11/0719-3]
- CAPES
- FINEP
Nucleophilic species of selenium were generated in situ from the reaction of diorganyl diselenide with NaBH4 in PEG-400 as solvent and selectively added to several alpha,beta-unsaturated ketones, esters, acid, and nitrile. By this simple procedure, chalcogenolate anions were directly added at mild conditions, furnishing the respective Michael adducts in good yields. (C) 2013 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据