期刊
TETRAHEDRON LETTERS
卷 54, 期 52, 页码 7183-7187出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2013.10.110
关键词
Organocatalysis; Cascade reactions; Thiohydantoins; Edman degradation; Diastereoselective
资金
- University of Southampton
- European Regional Development Fund (ERDF)
- AI-CHEM INTERREG IVb A France-(channel)-England
- European Regional Development Fund (ERDF) (AI-Chem Sz InterReg IVb)
A new three-component cascade reaction for the synthesis of thiohydantoins is reported. The reaction between alpha-amino esters, nitrostyrenes, and aromatic isothiocyanates is efficiently promoted by organic bases to afford highly substituted thiohydantoins in moderate to good yields and diastereoselectivities. (C) 2013 Elsevier Ltd. All rights reserved.
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