期刊
TETRAHEDRON LETTERS
卷 54, 期 8, 页码 970-974出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.12.046
关键词
Polymer-supported reagents; Polymer chemistry; Click chemistry; Green chemistry
资金
- Robert A. Welch Foundation [AJ-0029]
- Angelo State University Research Enhancement Foundation [0010-45564, 0100-60739]
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [1048553] Funding Source: National Science Foundation
The preparation of terminally functionalized atactic polypropylenes is described. Using standard organic transformations, an olefin terminated polypropylene oligomer could be converted into many other important functional groups. Such species can serve as useful polymer-bound building blocks for synthesis and catalysis. These supported derivatives exhibit high phase-selective solubility in nonpolar solvents, making them excellent candidates for use as supported reagents/catalysts. (C) 2012 Elsevier Ltd. All rights reserved.
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