期刊
TETRAHEDRON LETTERS
卷 53, 期 33, 页码 4313-4316出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.06.002
关键词
Pd-catalyzed; Reductive cleavage; Alkyl aryl sulfide; Triethylsilane; Trialkylsilyl chloride
资金
- Global COE program 'Center for Practical Chemical Wisdom' by MEXT
- [2105]
- Grants-in-Aid for Scientific Research [21106009, 24750096] Funding Source: KAKEN
The palladium-catalyzed reductive cleavage of alkyl aryl sulfides to afford the corresponding arenes in high yield, which is both accelerated and exhibits increased functional group selectivity in the presence of TMSCI, is described. This ligand-free reaction features mild conditions, easy operation, use of readily available reagents, and high functional group selectivity. (c) 2012 Elsevier Ltd. All rights reserved.
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