期刊
TETRAHEDRON LETTERS
卷 53, 期 51, 页码 6919-6922出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.10.019
关键词
[2+2]; Terpenoid; Cyclobutane; Carbocation; Quantum calculations
资金
- National Science Foundation
- Pittsburgh Supercomputer Center
Results from density functional theory calculations on a proton-promoted [2+2] cycloaddition to form plumisclerin A's cyclobutane ring are described. On the basis of these results, it is proposed that protonation allows for an energetically viable stepwise cycloaddition that provides an alternative to photochemical cyclobutane formation. (C) 2012 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据