4.4 Article

Copper-catalyzed tandem alkynylation, propargyl-allenyl isomerization, 6π-electrocyclization of Morita-Baylis-Hillman adducts to naphthalenes

期刊

TETRAHEDRON LETTERS
卷 53, 期 40, 页码 5449-5454

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.07.126

关键词

Morita-Baylis-Hillman adducts; Alkynylation; Propargyl-allenyl isomerization; 6 pi-Electrocyclization; Naphthalenes

资金

  1. Basic Science Research Program through the National Research Foundation of Korea (NRF)
  2. Ministry of Education, Science and Technology [2012R1A1B3000541]

向作者/读者索取更多资源

An expedient synthetic approach of naphthalenes was developed by the reaction of Morita-Baylis-Hillman bromides and arylacetylenes. The synthesis was carried out via a tandem copper-catalyzed alkynylation, propargyl-allenyl isomerization, and 6 pi-electrocyclization protocol. (C) 2012 Elsevier Ltd. All rights reserved.

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