期刊
TETRAHEDRON LETTERS
卷 53, 期 26, 页码 3342-3345出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.04.085
关键词
Oleocanthal; Samarium diiodide; Bromoalkyne-alkene coupling; Formal synthesis; Extra virgin olive oil
资金
- Grant for The Open Research Center Project
- Ministry of Education, Culture, Sports, Science and Technology of Japan
A novel approach to the synthesis of (-)-oleocanthal starting from D-ribose, in which a SmI2-promoted intramolecular coupling of bromoalkyne with alpha,beta-unsaturated ester is a key step, has been developed. (C) 2012 Elsevier Ltd. All rights reserved.
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