期刊
TETRAHEDRON LETTERS
卷 53, 期 29, 页码 3735-3738出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2012.04.118
关键词
(R)-Epichlorohydrin; Epoxidation; Lactonization; Ring closing metathesis (RCM); Grubb's catalyst
资金
- CSIR-UGC
A first total synthetic route has been reported for the synthesis of Phomolide G and H. The syntheses of fragments were initiated from commercially available and inexpensive starting material (R)-epichlorohydrin. The synthesis involves a key Sharpless epoxidation, stereoselective epoxide opening, lactonization and ring closing metathesis (RCM). (C) 2012 Elsevier Ltd. All rights reserved.
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