期刊
TETRAHEDRON LETTERS
卷 53, 期 4, 页码 395-398出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.11.043
关键词
Click chemistry; P-N ligands; Carbohydrates; Green chemistry; Pd-catalyzed allylic alkylation
资金
- Ministerio de Ciencia e Innovacion [CTQ2010-21755-CO2-00]
- Junta de Andalucia [P07-FQM-2774]
Reported is a modular approach for the synthesis of a number of structurally diverse ligands derived from carbohydrates. The use of the highly functional hydroxy amino azide 1 derived from glucosamine allows the synthesis of a number of useful ligands for organic and organometallic catalyses. The key step of the approach is the Huisgen cycloaddition of the anomeric sugar azide and diverse alkynes. (C) 2011 Elsevier Ltd. All rights reserved.
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