4.4 Article

A novel BINOL-based cyclophane via click chemistry: synthesis and its applications for sensing silver ions

期刊

TETRAHEDRON LETTERS
卷 52, 期 38, 页码 4927-4930

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.07.050

关键词

BINOL; Cyclophane; Click chemistry; Fluorescent sensor; Ag+

资金

  1. National Science Foundation of China [20725206, 20732004, 21021001]
  2. Program for Changjiang Scholars and Innovative Research Team in University
  3. Chinese Ministry of Education in China
  4. Scientific Fund of Sichuan Province for Outstanding Young Scientist

向作者/读者索取更多资源

A novel BINOL-based cyclophane 1 incorporating two triazole moieties was synthesized via click chemistry and characterized. Among the metal ions screened, only Ag+ was found to have the ability to quench the fluorescence of 1 in methanol solution. The 1:1 binding mode of 1-Ag+ was confirmed. The competitive experiment showed that compound 1 can be used as a specific fluorescent sensor for Ag+ over a wide range of competing cations. (C) 2011 Elsevier Ltd. All rights reserved.

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