期刊
TETRAHEDRON LETTERS
卷 52, 期 46, 页码 6185-6189出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.09.050
关键词
Peptide nucleic acid; Click chemistry; Microwave chemistry; Synthesis design
We describe in this Letter the synthesis of an original thymine azido-heterotrimer generated by Click Chemistry. This trimer has been obtained from an azido-thymidine and a new chloroethyl-propargylated PNA monomer analogue, after two azidation/click-reaction cycles. Conformational preferences of a rotameric intermediate have also been studied (C) 2011 Elsevier Ltd. All rights reserved.
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