期刊
TETRAHEDRON LETTERS
卷 52, 期 5, 页码 619-622出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.11.157
关键词
Asymmetric catalysis; Continuous-flow processes; Microreactors; Organocatalysis
资金
- Italian Ministry of University and Scientific Research [RBPR05NWWC 008]
The activity and stability under flow conditions of covalently and non-covalently silica supported proline and proline-like organocatalysts is herein described. The slow aldol reaction of cyclohexanone with p-nitro benzaldehyde and the fast alpha-amination of isovaleraldehyde with dibenzyl azodicarboxylate have been selected as model reactions for this study. Prospects and limitations of the disclosed continuous-flow organocatalytic approach are widely discussed. (C) 2010 Elsevier Ltd. All rights reserved.
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