期刊
TETRAHEDRON LETTERS
卷 52, 期 6, 页码 692-695出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.12.004
关键词
Aerobic oxidation; Zinc catalyst; Molecular oxygen; Kinetic resolution; Enantioselective oxidation
资金
- DST, New Delhi [SR/S1/OC-06/2008]
- UGC, New Delhi
Zn(II)-DABCO complex is used as an efficient catalyst for the aerobic oxidation of benzoins to benzils in the presence of molecular oxygen. Usage of chiral zinc complex as catalyst resulted in enantioselective oxidative kinetic resolution of racemic benzoin to yield enantiomerically enriched benzoins. (C) 2010 Elsevier Ltd. All rights reserved.
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