期刊
TETRAHEDRON LETTERS
卷 52, 期 33, 页码 4243-4246出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.05.137
关键词
Spiro imines; Gymnodimine; Spirolide; Alexandrium peruvianum
资金
- NIH [5P41GM076300-01]
- MARBI-ONC
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [0821552] Funding Source: National Science Foundation
The novel gymnodimine congener 12-methylgymnodimine was isolated from the dinoflagellate Alexandrium peruvianum from the New River in North Carolina. In addition, the presence of 13-desmethylspirolide C was confirmed by NMR characterization. This marks the first time these two classes of cyclic imines have been found in the same organism, providing further evidence for a direct genetic relationship between the biosynthetic pathways for gymnodimines and spirolides suggested by comparison of their structures. (C) 2011 Elsevier Ltd. All rights reserved.
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