期刊
TETRAHEDRON LETTERS
卷 52, 期 52, 页码 7157-7160出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.10.123
关键词
Microwave-assisted organic synthesis; aza-Prins reaction; Diastereoselective synthesis; Bicyclic piperidines; Lycopodium alkaloids; Complexity-generating synthesis
资金
- Federal Agency for Science and Innovation (Russian Federation Government) [02.740.11.0092]
A facile and operationally simple route to diastereomerically pure, natural-like 3-azabicyclo[3.3.1]non-6-enes via microwave-assisted, BF3 center dot OEt2-promoted aza-Prins reaction has been developed. Complexity-generating transformations based on these products involving reactive functionalities introduced during the aza-Prins step have been developed. (C) 2011 Elsevier Ltd. All rights reserved.
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