4.4 Article

Metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides

期刊

TETRAHEDRON LETTERS
卷 52, 期 13, 页码 1430-1431

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.11.103

关键词

C-N formation; Arylboronic acids; Organic azides; Metal-free

资金

  1. National Natural Science Foundation of China [30772652, 90813026]
  2. National key Tech project for Major Creation of New Drugs [2009ZX09501-010]

向作者/读者索取更多资源

A novel and efficient metal-free carbon-nitrogen bond-forming coupling reaction between arylboronic acids and organic azides is reported. The reaction is fairly general for the preparation of secondary aromatic amines. Furthermore, the reaction is very functional-group tolerant. A possible mechanism is also proposed. (c) 2011 Elsevier Ltd. All rights reserved.

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