期刊
TETRAHEDRON LETTERS
卷 52, 期 15, 页码 1733-1737出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2011.02.021
关键词
Matsuda-Heck arylation; Imidazolium ionic liquids; Arenediazonium salts; Olefin synthesis; One-pot diazotization-arylation
资金
- University of North Florida
The utility of arenediazonium salts immobilized in imidazolium-ILs [BMIMPF6 and BMIMBF4] for facile, high yielding, synthesis of olefins via the Pd(OAc)(2)-catalyzed Matsuda-Heck arylation reaction has been demonstrated. The reaction can also be performed as a two-step process in the IL starting from ArNH2, by sequential in-situ diazotization-arylation. Simple product isolation and the recycling/re-use of the IL are additional advantages of this one-pot method. (C) 2011 Elsevier Ltd. All rights reserved.
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