期刊
TETRAHEDRON LETTERS
卷 51, 期 18, 页码 2450-2452出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.02.150
关键词
Oxidation reaction; Vanadium catalyst; Amines; Atmospheric oxygen
资金
- Ministry of Education, Culture, Sports, Science and Technology, Japan
- Kansai Research Foundation for Technology Promotion (KRF)
- Japan Society for the Promotion of Science (JSPS)
Oxovanadium complex bearing 3-hydroxypicolinic acid (H(2)hpic), that is, VO(Hhpic)(2), successfully catalyzes a highly selective oxidation of benzylamines to the corresponding N-(benzylidene)benzylamines under atmospheric molecular oxygen. In addition, the use of imidazolium-type ionic liquids as solvent makes it possible to attain recycling of the catalyst. (C) 2010 Elsevier Ltd. All rights reserved.
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