期刊
TETRAHEDRON LETTERS
卷 51, 期 42, 页码 5615-5617出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.08.068
关键词
Hypochlorite; Hydroperoxyacetal; Chloroperoxide; Fragmentation; Ester
资金
- NSF [CH-0749916, MRI 0079750, CHE 0091975]
- NIH [RR016544-01]
- Nebraska Research Initiative
Hypochlorites efficiently dehydrate hydroperoxyacetals to furnish the corresponding esters. The reaction, which can be accomplished with stoichometric Ca(OCl)(2) or with catalytic amounts of t-BuOCl, appears to involve formation and heterolytic fragmentation of secondary chloroperoxides, species not previously described in solution chemistry. (c) 2010 Elsevier Ltd. All rights reserved.
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