期刊
TETRAHEDRON LETTERS
卷 51, 期 12, 页码 1566-1569出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2010.01.055
关键词
Epoxides; 1,3-Dicarbonyl compounds; Solid bases; Solvent-free conditions (SolFCs)
资金
- Ministero dell'lstruzione dell'Universita e della Ricerca (MIUR)
- Universita degli Studi di Perugia
This contribution reports the results obtained in the definition of a catalytic method for the nucleophilic ring opening of epoxides by activated methylenes promoted by a polymer-supported base. The attention has been focused oil the use of polymer supported bases and the best results have been obtained by using 4-(dimethylamino)pyridine (PS-DMAP) and 2-tert-butylimino-2-diethylamino-1,3-dimethyl-perhydro-1,3,2-diazaphosphorine both oil polystyrene (PS-BEMP). Solvent-free conditions has been essential for reaching a sufficient reactivity to realize this process, in fact when a reaction medium is used, the processes are almost unfeasible. (C) 2010 Elsevier Ltd. All rights reserved.
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