期刊
TETRAHEDRON LETTERS
卷 51, 期 13, 页码 1648-1650出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.12.095
关键词
-
资金
- National Institutes of Health [GM069441]
It was observed that the relative position of the arene substituents has a profound influence on the strength of pi-pi stacking in the 9-benzyl-substituted triptycene system. A new series of model compounds (3a-i) capable of revealing quantitatively pi-pi stacking interactions was studied. This series of compounds (3a-i) has an ortho-substituted methyl group in one of the two interacting arenes and the syn/anti ratios were determined and compared to a series previously studied compounds (4a-i) that have a para methyl group on the corresponding arene. A greater than 50% increase in the strength of pi-pi stacking interactions was observed with the methyl group in the ortho position comparing to that in the para position. No difference in pi-pi stacking interactions was observed when the other aromatic ring was a pentafluorobenzoate group. (C) 2009 Elsevier Ltd. All rights reserved.
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