期刊
TETRAHEDRON LETTERS
卷 51, 期 1, 页码 46-48出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.10.063
关键词
Polymethylhydrosiloxane; Molecular iodine; Carbonyl compounds; Reductive etherification; Ethers
资金
- CSIR, New Delhi
Aldehydes and ketones undergo a smooth reductive etherification by polymethylhydrosiloxane (PMHS) in the presence of a catalytic amount of molecular iodine under mild conditions to afford the corresponding symmetrical ethers in excellent yields. This new reagent system (PMHS/I(2)) provides a simple and convenient route for the preparation of symmetrical ethers from carbonyl compounds (C) 2009 Elsevier Ltd. All rights reserved.
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