期刊
TETRAHEDRON LETTERS
卷 50, 期 47, 页码 6484-6487出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.09.019
关键词
Exo-Glycals; Vinylic bromide; Palladium cross-coupling; C-Glycosyl
Efficient methods of preparation of disubstituted exo-glycals by palladium cross-coupling reaction on the readily available dibromo exo-glycal and methoxycarbonyl exa-glycal have been developed. Hydrogenation of these new monosubstituted and disubstituted exo-glycals proceeded with a high stereocontrol and led to original C-glycosyl compounds. (C) 2009 Elsevier Ltd All rights reserved.
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