期刊
TETRAHEDRON LETTERS
卷 50, 期 32, 页码 4602-4605出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.tetlet.2009.05.065
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资金
- Ministry of Education, Culture, Sports, Science, and Technology, Japan
Chiral phosphine oxide successfully catalyzed the direct aldol-type reactions of cyclohexanone derivatives and benzaldehyde derivatives in high stereoselectivities. The reaction mechanism involves the in situ formation of trichlorosilyl enol ethers. The present reaction could be extended to the cross-aldol reactions between two aldehydes. (C) 2009 Elsevier Ltd. All rights reserved.
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